LiFe is a less volatile chemistry, compared to LiPo. The problem is, it weighs a lot more, compared to a LiPo.
To get the equivalent voltage of a 2s LiPo pack, for example, your LiFe pack is going to weigh a lot more.
If you want to learn more about batteries and chargers in general, check out just about any thread in the Batteries and Chargers forum:
For some reason, they tuck it under the Aircraft forums, which I think is a great disservice to the rest of the community, since there are many forum users who don't fly, but would still benefit from the knowledge in that forum.
It is an excellent resource for battery and charger information. Among the best in the web that I have been able to find, imo.
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